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Table of contents

E1012 Organic Free Radicals under Hydrothermal Conditions

The Phase Diagram of Water

Supercritical Water

A Flame in Water!

Slide 5

Muonium Chemistry in sub- and supercritical water

Apparatus for Hydrothermal Studies in HELIOS

Organic Chemical Reactions in Supercritical Water

Studying Reactions in High Temperature Water is Difficult

Muonium (Mu) a light isotope of Hydrogen

Muoniated Free Radicals

Transverse Field Muon Spin Rotation

Slide 13

Fourier Power µSR Spectrum of tert-Butyl in Water

Avoided Muon Level Crossing Resonance

tert-Butyl Radical in Water

Muon Hyperfine Constant of (CH3)2CH2Mu in Solution

tert-Butyl Radical in Water, from 380°C down to 40°C

Dynamics of the Muoniated tert-butyl Radical

Temperature Dependence of hfcs in tert-butyl

Acetone

Acetone in Water ï‚® Different Radicals at Low and High Temperatures

Slide 23

How to Study a keto-enol Equilibrium by Radical Trapping

The enol Adduct of Acetone in Water

Mu adduct of the keto form of Acetone in Water

Muoniated Radical from 1,3-Butandiol in Water

Slide 28

Slide 29

Slide 30

Summary of Proposed Experiments

Slide 32

Acknowledgements

Slide 34

H + OH ï‚® H2O

Muonium in Supercritical Water

Author: Paul Percival

E-mail: percival@sfu.ca